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</span></dd> <div class="xq_content"> <br /> <section class="text-xmyeditor" style="margin-bottom:unset;"><section data-id="59711" class="xmyeditor style_1" data-tools="小墨鷹編輯器" powered-by="xmyeditor.com" data-type="lspecial02" data-md5="8a4b0" style="box-sizing: border-box; max-width: 100% !important;"><section class="wxqq-borderBottomColor wxqq-borderTopColor wxqq-borderRightColor wxqq-borderLeftColor xmy-banone xmy-dunluo style_2" style="border: 1px solid rgb(255, 179, 186); border-radius: 10px; box-sizing: border-box; padding: 5px 20px; background-color: rgb(255, 255, 255); max-width: 100% !important;" powered-by="xmyeditor.com" data-md5="8a4b0"><section class="xmyeditor style_3" powered-by="xmyeditor.com" data-type="lspecial01,lspecial06" data-md5="8a4b0" style="box-sizing: border-box; max-width: 100% !important;"><section style="padding: 10px 0px; box-sizing: border-box; max-width: 100% !important;" powered-by="xmyeditor.com" class="xmy-dunluo style_4" data-md5="8a4b0"><section class="xmyeditor buchai style_5" powered-by="xmyeditor.com" data-md5="8a4b0" style="box-sizing: border-box; max-width: 100% !important;"><section style="box-sizing: border-box; max-width: 100% !important;" powered-by="xmyeditor.com" data-md5="8a4b0" class="style_6"><section style="display: inline-block; vertical-align: middle; box-sizing: border-box; max-width: 100% !important;" powered-by="xmyeditor.com" data-md5="8a4b0" class="style_7"><section style="display: flex; align-items: center; justify-content: center; box-sizing: border-box; max-width: 100% !important;" powered-by="xmyeditor.com" data-md5="8a4b0" class="style_8"><section class="xmyeditor buchai style_9" powered-by="xmyeditor.com" data-md5="8a4b0" style="box-sizing: border-box; max-width: 100% !important;"><section style="width: 20px; height: 20px; background-color: rgb(255, 179, 186); border-radius: 50%; box-sizing: border-box; padding: 2px 0px 0px; transform: rotate(-45deg); max-width: 100% !important;" powered-by="xmyeditor.com" class="xmy-banone xmy-dunluo style_10" data-md5="8a4b0"><section class="wxqq-bg xmy-banone style_11" style="width: 20px; height: 20px; background-color: rgb(255, 112, 117); border-radius: 50%; box-sizing: border-box; max-width: 100% !important;" powered-by="xmyeditor.com" data-md5="8a4b0"><section style="color: rgb(255, 255, 255); letter-spacing: 1.5px; line-height: 20px; text-align: center; transform: rotate(45deg); box-sizing: border-box; max-width: 100% !important;" powered-by="xmyeditor.com" data-md5="8a4b0" class="style_12"><p style="padding: 0px; margin-top: 0px; margin-bottom: 0px;" data-md5="8a4b0" class="style_13"><strong class="autosort style_14" style="font-size: 13px;line-height: 20px;" data-md5="8a4b0">1</strong></p></section></section></section></section><section style="flex: 1 1 0%; margin-left: 10px; box-sizing: border-box; max-width: 100% !important;" powered-by="xmyeditor.com" data-md5="8a4b0" class="style_15"><section class="wxqq-Color style_16" style="color: rgb(58, 66, 65); letter-spacing: 1.5px; line-height: 24px; text-align: justify; box-sizing: border-box; max-width: 100% !important;" powered-by="xmyeditor.com" data-md5="8a4b0"><p class="xmybrush style_17" style="padding: 0px; margin-top: 0px; margin-bottom: 0px;" data-md5="8a4b0"><span class="" style="font-size: 15px;"><strong>常見的鋯化劑成分</strong></span></p></section></section></section></section></section></section><section class="xmyeditor buchai style_19" powered-by="xmyeditor.com" data-md5="8a4b0" style="box-sizing: border-box; max-width: 100% !important;"><section class="wxqq-Color style_20" style="color: rgb(74, 97, 97); letter-spacing: 1.5px; line-height: 24px; text-align: justify; margin-top: 5px; box-sizing: border-box; max-width: 100% !important;" powered-by="xmyeditor.com" data-md5="8a4b0"><p class="xmybrush style_21" style="padding: 0px; margin-top: 0px; margin-bottom: 0px; font-size: 13px; text-align: center;" data-md5="8a4b0"><img src="http://www.jujiazdh.com/uploads/allimg/240823/0933306142-0.png" data-cropselew="452" data-cropseleh="135.125" style="max-width: 100% !important;"/></p><p style="line-height: 1.5; text-indent: 2em;"><span class="" style="font-size: 15px; color: rgb(0, 0, 0); line-height: 1.5;">根據上表所列的資料分析，氟鋯酸（銨）是鋯化劑的常見組分。</span><br style="line-height: 1.5;"/></p></section></section></section></section><section class="xmyeditor style_22" powered-by="xmyeditor.com" data-type="lspecial01,lspecial06" data-md5="8a4b0" style="box-sizing: border-box; max-width: 100% !important;"><section style="padding: 10px 0px; box-sizing: border-box; max-width: 100% !important;" powered-by="xmyeditor.com" class="xmy-dunluo style_23" data-md5="8a4b0"><section class="xmyeditor buchai style_24" powered-by="xmyeditor.com" data-md5="8a4b0" style="box-sizing: border-box; max-width: 100% !important;"><section style="box-sizing: border-box; max-width: 100% !important;" powered-by="xmyeditor.com" data-md5="8a4b0" class="style_25"><section style="display: inline-block; vertical-align: middle; box-sizing: border-box; max-width: 100% !important;" powered-by="xmyeditor.com" data-md5="8a4b0" class="style_26"><section style="display: flex; align-items: center; justify-content: center; box-sizing: border-box; max-width: 100% !important;" powered-by="xmyeditor.com" data-md5="8a4b0" class="style_27"><section class="xmyeditor buchai style_28" powered-by="xmyeditor.com" data-md5="8a4b0" style="box-sizing: border-box; max-width: 100% !important;"><section style="width: 20px; height: 20px; background-color: rgb(255, 179, 186); border-radius: 50%; box-sizing: border-box; padding: 2px 0px 0px; transform: rotate(-45deg); max-width: 100% !important;" powered-by="xmyeditor.com" class="xmy-banone xmy-dunluo style_29" data-md5="8a4b0"><section class="wxqq-bg xmy-banone style_30" style="width: 20px; height: 20px; background-color: rgb(255, 112, 117); border-radius: 50%; box-sizing: border-box; max-width: 100% !important;" powered-by="xmyeditor.com" data-md5="8a4b0"><section style="color: rgb(255, 255, 255); letter-spacing: 1.5px; line-height: 20px; text-align: center; transform: rotate(45deg); box-sizing: border-box; max-width: 100% !important;" powered-by="xmyeditor.com" data-md5="8a4b0" class="style_31"><p style="padding: 0px; margin-top: 0px; margin-bottom: 0px;" data-md5="8a4b0" class="style_32"><strong class="autosort style_33" style="font-size: 13px;line-height: 20px;" data-md5="8a4b0">2</strong></p></section></section></section></section><section style="flex: 1 1 0%; margin-left: 10px; box-sizing: border-box; max-width: 100% !important;" powered-by="xmyeditor.com" data-md5="8a4b0" class="style_34"><section class="wxqq-Color style_35" style="color: rgb(58, 66, 65); letter-spacing: 1.5px; line-height: 24px; text-align: justify; box-sizing: border-box; max-width: 100% !important;" powered-by="xmyeditor.com" data-md5="8a4b0"><p class="xmybrush style_36" style="padding: 0px; margin-top: 0px; margin-bottom: 0px;" data-md5="8a4b0"><span class="" style="font-size: 15px;"><strong>鋯化前處理反應過程</strong></span></p></section></section></section></section></section></section><section class="xmyeditor buchai style_38" powered-by="xmyeditor.com" data-md5="8a4b0" style="box-sizing: border-box; max-width: 100% !important;"><section class="wxqq-Color style_39" style="color: rgb(74, 97, 97); letter-spacing: 1.5px; line-height: 24px; text-align: justify; margin-top: 5px; box-sizing: border-box; max-width: 100% !important;" powered-by="xmyeditor.com" data-md5="8a4b0"><p style="line-height: 1.5; text-indent: 2em;"><span class="" style="font-size: 15px; color: rgb(0, 0, 0); line-height: 1.5;">曹獻龍等研究者在《鋼鐵表面純鋯鹽轉化膜技術研究現狀與進展》[1]一文中報道：在前處理過程中，氟鋯酸或鋯鹽在促進劑、調整劑配合下，與金屬基材直接反應，生產的二氧化鋯膜層覆蓋在金屬基材表面，達到防腐的目的。主要反應過程如下：</span></p><p style="text-align: center; line-height: 1.5;"><img style="vertical-align: inherit; line-height: 1.5; max-width: 100% !important;" src="http://www.jujiazdh.com/uploads/allimg/240823/0933305638-1.png" alt="image.png" data-cropselew="446" data-cropseleh="399"/></p><p style="line-height: 1.5; text-indent: 2em;"><span class="" style="font-size: 15px; color: rgb(0, 0, 0); line-height: 1.5;">經上述反應后，金屬基材表面會形成一種“ZrO2-Fe-ZrO2”結構的溶膠。隨著反應的進行，溶膠的交聯密度逐漸增大，不斷凝聚沉積，最終形成連續致密的ZrO2膜層。鋼鐵表面鋯鹽轉化成膜過程原理如下圖：</span></p><p class="xmybrush style_40" style="padding: 0px; margin-top: 0px; margin-bottom: 0px; font-size: 13px; line-height: 1.5; text-align: center;" data-md5="8a4b0"><span style="color: rgb(58, 58, 58); font-family: "IBM Plex Sans", sans-serif; font-size: 16px; letter-spacing: normal; text-align: justify; text-indent: 32px; line-height: 1.5;"><img src="http://www.jujiazdh.com/uploads/allimg/240823/093330D63-2.jpg" style="line-height: 1.5; max-width: 100% !important;" data-cropselew="452" data-cropseleh="246.078"/></span><br style="line-height: 1.5;"/></p></section></section></section></section><section class="xmyeditor style_22" powered-by="xmyeditor.com" data-type="lspecial01,lspecial06" data-md5="8a4b0" style="box-sizing: border-box; max-width: 100% !important;"><section style="padding: 10px 0px; box-sizing: border-box; max-width: 100% !important;" powered-by="xmyeditor.com" class="xmy-dunluo style_23" data-md5="8a4b0"><section class="xmyeditor buchai style_24" powered-by="xmyeditor.com" data-md5="8a4b0" style="box-sizing: border-box; max-width: 100% !important;"><section style="box-sizing: border-box; max-width: 100% !important;" powered-by="xmyeditor.com" data-md5="8a4b0" class="style_25"><section style="display: inline-block; vertical-align: middle; box-sizing: border-box; max-width: 100% !important;" powered-by="xmyeditor.com" data-md5="8a4b0" class="style_26"><section style="display: flex; align-items: center; justify-content: center; box-sizing: border-box; max-width: 100% !important;" powered-by="xmyeditor.com" data-md5="8a4b0" class="style_27"><section class="xmyeditor buchai style_28" powered-by="xmyeditor.com" data-md5="8a4b0" style="box-sizing: border-box; max-width: 100% !important;"><section style="width: 20px; height: 20px; background-color: rgb(255, 179, 186); border-radius: 50%; box-sizing: border-box; padding: 2px 0px 0px; transform: rotate(-45deg); max-width: 100% !important;" powered-by="xmyeditor.com" class="xmy-banone xmy-dunluo style_29" data-md5="8a4b0"><section class="wxqq-bg xmy-banone style_30" style="width: 20px; height: 20px; background-color: rgb(255, 112, 117); border-radius: 50%; box-sizing: border-box; max-width: 100% !important;" powered-by="xmyeditor.com" data-md5="8a4b0"><section style="color: rgb(255, 255, 255); letter-spacing: 1.5px; line-height: 20px; text-align: center; transform: rotate(45deg); box-sizing: border-box; max-width: 100% !important;" powered-by="xmyeditor.com" data-md5="8a4b0" class="style_31"><p style="padding: 0px; margin-top: 0px; margin-bottom: 0px;" data-md5="8a4b0" class="style_32"><strong class="autosort style_33" style="font-size: 13px;line-height: 20px;" data-md5="8a4b0">3</strong></p></section></section></section></section><section style="flex: 1 1 0%; margin-left: 10px; box-sizing: border-box; max-width: 100% !important;" powered-by="xmyeditor.com" data-md5="8a4b0" class="style_34"><section class="wxqq-Color style_35" style="color: rgb(58, 66, 65); letter-spacing: 1.5px; line-height: 24px; text-align: justify; box-sizing: border-box; max-width: 100% !important;" powered-by="xmyeditor.com" data-md5="8a4b0"><p class="xmybrush style_36" style="padding: 0px; margin-top: 0px; margin-bottom: 0px; line-height: 1.5;" data-md5="8a4b0"><span class="" style="font-size: 15px; color: rgb(0, 0, 0); line-height: 1.5;"><strong style="line-height: 1.5;">鋯化前處理工藝流程</strong></span></p></section></section></section></section></section></section><section class="xmyeditor buchai style_38" powered-by="xmyeditor.com" data-md5="8a4b0" style="box-sizing: border-box; max-width: 100% !important;"><section class="wxqq-Color style_39" style="color: rgb(74, 97, 97); letter-spacing: 1.5px; line-height: 24px; text-align: justify; margin-top: 5px; box-sizing: border-box; max-width: 100% !important;" powered-by="xmyeditor.com" data-md5="8a4b0"><p style="line-height: 1.5; text-indent: 2em;"><span class="" style="font-size: 15px; color: rgb(0, 0, 0); line-height: 1.5;">鋯化前處理的典型工藝流程如下圖所示：</span></p><p class="xmybrush style_40" style="padding: 0px; margin-top: 0px; margin-bottom: 0px; font-size: 13px; line-height: 1.5; text-align: center;" data-md5="8a4b0"><span style="color: rgb(58, 58, 58); font-family: "IBM Plex Sans", sans-serif; font-size: 16px; letter-spacing: normal; text-align: justify; text-indent: 32px; line-height: 1.5;"><img src="http://www.jujiazdh.com/uploads/allimg/240823/0933306452-3.png" data-cropselew="452" data-cropseleh="502.672" style="line-height: 1.5; max-width: 100% !important;"/><br style="line-height: 1.5;"/></span></p></section></section></section></section><section class="xmyeditor style_22" powered-by="xmyeditor.com" data-type="lspecial01,lspecial06" data-md5="8a4b0" style="box-sizing: border-box; max-width: 100% !important;"><section style="padding: 10px 0px; box-sizing: border-box; max-width: 100% !important;" powered-by="xmyeditor.com" class="xmy-dunluo style_23" data-md5="8a4b0"><section class="xmyeditor buchai style_24" powered-by="xmyeditor.com" data-md5="8a4b0" style="box-sizing: border-box; max-width: 100% !important;"><section style="box-sizing: border-box; max-width: 100% !important;" powered-by="xmyeditor.com" data-md5="8a4b0" class="style_25"><section style="display: inline-block; vertical-align: middle; box-sizing: border-box; max-width: 100% !important;" powered-by="xmyeditor.com" data-md5="8a4b0" class="style_26"><section style="display: flex; align-items: center; justify-content: center; box-sizing: border-box; max-width: 100% !important;" powered-by="xmyeditor.com" data-md5="8a4b0" class="style_27"><section class="xmyeditor buchai style_28" powered-by="xmyeditor.com" data-md5="8a4b0" style="box-sizing: border-box; max-width: 100% !important;"><section style="width: 20px; height: 20px; background-color: rgb(255, 179, 186); border-radius: 50%; box-sizing: border-box; padding: 2px 0px 0px; transform: rotate(-45deg); max-width: 100% !important;" powered-by="xmyeditor.com" class="xmy-banone xmy-dunluo style_29" data-md5="8a4b0"><section class="wxqq-bg xmy-banone style_30" style="width: 20px; height: 20px; background-color: rgb(255, 112, 117); border-radius: 50%; box-sizing: border-box; max-width: 100% !important;" powered-by="xmyeditor.com" data-md5="8a4b0"><section style="color: rgb(255, 255, 255); letter-spacing: 1.5px; line-height: 20px; text-align: center; transform: rotate(45deg); box-sizing: border-box; max-width: 100% !important;" powered-by="xmyeditor.com" data-md5="8a4b0" class="style_31"><p style="padding: 0px; margin-top: 0px; margin-bottom: 0px;" data-md5="8a4b0" class="style_32"><strong class="autosort style_33" style="font-size: 13px;line-height: 20px;" data-md5="8a4b0">4</strong></p></section></section></section></section><section style="flex: 1 1 0%; margin-left: 10px; box-sizing: border-box; max-width: 100% !important;" powered-by="xmyeditor.com" data-md5="8a4b0" class="style_34"><section class="wxqq-Color style_35" style="color: rgb(58, 66, 65); letter-spacing: 1.5px; line-height: 24px; text-align: justify; box-sizing: border-box; max-width: 100% !important;" powered-by="xmyeditor.com" data-md5="8a4b0"><p class="xmybrush style_36" data-md5="8a4b0"><strong><span class="" style="font-size: 15px; color: rgb(0, 0, 0);">常被遺忘的鋯化廢水特征污染物</span></strong></p></section></section></section></section></section></section><section class="xmyeditor buchai style_38" powered-by="xmyeditor.com" data-md5="8a4b0" style="box-sizing: border-box; max-width: 100% !important;"><section class="wxqq-Color style_39" style="color: rgb(74, 97, 97); letter-spacing: 1.5px; line-height: 24px; text-align: justify; margin-top: 5px; box-sizing: border-box; max-width: 100% !important;" powered-by="xmyeditor.com" data-md5="8a4b0"><p style="line-height: 1.5; text-indent: 2em;"><span class="" style="font-size: 15px; color: rgb(0, 0, 0); line-height: 1.5;">根據上圖，鋯化前處理廢水主要包括以下幾股：</span></p><p style="line-height: 1.5; text-indent: 2em;"><span class="" style="font-size: 15px; color: rgb(0, 0, 0); line-height: 1.5;">1.沖洗廢水</span></p><p style="line-height: 1.5; text-indent: 2em;"><span class="" style="font-size: 15px; color: rgb(0, 0, 0); line-height: 1.5;">2.脫脂廢水</span></p><p style="line-height: 1.5; text-indent: 2em;"><span class="" style="font-size: 15px; color: rgb(0, 0, 0); line-height: 1.5;">3.脫脂后清洗廢水</span></p><p style="line-height: 1.5; text-indent: 2em;"><span class="" style="font-size: 15px; color: rgb(0, 0, 0); line-height: 1.5;">4.鋯化廢水</span></p><p style="line-height: 1.5; text-indent: 2em;"><span class="" style="font-size: 15px; color: rgb(0, 0, 0); line-height: 1.5;">5.鋯化后清洗廢水</span></p><p style="line-height: 1.5; text-indent: 2em;"><span class="" style="font-size: 15px; color: rgb(0, 0, 0); line-height: 1.5;">在環評工作中，鋯化廢水常常不被重視，其特征污染物往往會被忽略。鋯化廢水特征污染物的種類與鋯化劑的成分及鋯化反應的特點有關?！丁磁盼蹎挝蛔孕斜O測技術指南涂裝（征求意見稿）〉編制說明》中提到，“…（鋯化）廢水主要污染物是 pH 及氟化物?！倍谝颜筋C布的《排污許可證申請與核發技術規范汽車制造業》（HJ 971-2018）、《排污許可證申請與核發技術規范鐵路、船舶、航空航天和其他運輸設備制造業》（HJ 1124-2020）、《排污單位自行監測技術指南涂裝》（HJ 1086-2020）中，氟化物均作為鋯化廢水的監測指標再三確認。因此，在環評工作中，我們應將氟化物列為鋯化前處理工藝的重要特征污染物予以評價。</span></p></section></section></section></section><section class="xmyeditor style_22" powered-by="xmyeditor.com" data-type="lspecial01,lspecial06" data-md5="8a4b0" style="box-sizing: border-box; max-width: 100% !important;"><section style="padding: 10px 0px; box-sizing: border-box; max-width: 100% !important;" powered-by="xmyeditor.com" class="xmy-dunluo style_23" data-md5="8a4b0"><section class="xmyeditor buchai style_24" powered-by="xmyeditor.com" data-md5="8a4b0" style="box-sizing: border-box; max-width: 100% !important;"><section style="box-sizing: border-box; max-width: 100% !important;" powered-by="xmyeditor.com" data-md5="8a4b0" class="style_25"><section style="display: inline-block; vertical-align: middle; box-sizing: border-box; max-width: 100% !important;" powered-by="xmyeditor.com" data-md5="8a4b0" class="style_26"><section style="display: flex; align-items: center; justify-content: center; box-sizing: border-box; max-width: 100% !important;" powered-by="xmyeditor.com" data-md5="8a4b0" class="style_27"><section class="xmyeditor buchai style_28" powered-by="xmyeditor.com" data-md5="8a4b0" style="box-sizing: border-box; max-width: 100% !important;"><section style="width: 20px; height: 20px; background-color: rgb(255, 179, 186); border-radius: 50%; box-sizing: border-box; padding: 2px 0px 0px; transform: rotate(-45deg); max-width: 100% !important;" powered-by="xmyeditor.com" class="xmy-banone xmy-dunluo style_29" data-md5="8a4b0"><section class="wxqq-bg xmy-banone style_30" style="width: 20px; height: 20px; background-color: rgb(255, 112, 117); border-radius: 50%; box-sizing: border-box; max-width: 100% !important;" powered-by="xmyeditor.com" data-md5="8a4b0"><section style="color: rgb(255, 255, 255); letter-spacing: 1.5px; line-height: 20px; text-align: center; transform: rotate(45deg); box-sizing: border-box; max-width: 100% !important;" powered-by="xmyeditor.com" data-md5="8a4b0" class="style_31"><p style="padding: 0px; margin-top: 0px; margin-bottom: 0px;" data-md5="8a4b0" class="style_32"><strong class="autosort style_33" style="font-size: 13px;line-height: 20px;" data-md5="8a4b0">5</strong></p></section></section></section></section><section style="flex: 1 1 0%; margin-left: 10px; box-sizing: border-box; max-width: 100% !important;" powered-by="xmyeditor.com" data-md5="8a4b0" class="style_34"><section class="wxqq-Color style_35" style="color: rgb(58, 66, 65); letter-spacing: 1.5px; line-height: 24px; text-align: justify; box-sizing: border-box; max-width: 100% !important;" powered-by="xmyeditor.com" data-md5="8a4b0"><p class="xmybrush style_36" style="padding: 0px; margin-top: 0px; margin-bottom: 0px;" data-md5="8a4b0"><span class="" style="font-size: 15px; color: rgb(0, 0, 0);"><strong>參考文獻</strong></span></p></section></section></section></section></section></section><section class="xmyeditor buchai style_38" powered-by="xmyeditor.com" data-md5="8a4b0" style="box-sizing: border-box; max-width: 100% !important;"><section class="wxqq-Color style_39" style="color: rgb(74, 97, 97); letter-spacing: 1.5px; line-height: 24px; text-align: justify; margin-top: 5px; box-sizing: border-box; max-width: 100% !important;" powered-by="xmyeditor.com" data-md5="8a4b0"><p style="line-height: 1.5; text-indent: 2em;"><span class="" style="font-size: 15px; color: rgb(0, 0, 0); line-height: 1.5;">[1]曹獻龍,孫培入,劉洋,徐光旭,高正源,鄧洪達,蘭偉.鋼鐵表面純鋯鹽轉化膜技術研究現狀與進展[J].表面技術,2017,46(08):72-78.</span></p></section></section></section></section></section></section><section class="text-xmyeditor" 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